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Beschreibung
The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective FujiwaräMoritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.
Control of Alkene Geometry or Relative Configuration
Details
| Verlag | LAP LAMBERT Academic Publishing |
| Ersterscheinung | 14. August 2013 |
| Maße | 22 cm x 15 cm x 1.8 cm |
| Gewicht | 435 Gramm |
| Format | Softcover |
| ISBN-13 | 9783848498802 |
| Seiten | 280 |
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