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Beschreibung
This thesis investigates the early ignition behavior of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition. Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer–clay interfacial interaction.
Details
| Verlag | Springer Singapore |
| Ersterscheinung | 25. Dezember 2018 |
| Maße | 23.5 cm x 15.5 cm |
| Gewicht | 312 Gramm |
| Format | Softcover |
| ISBN-13 | 9789811341243 |
| Auflage | Softcover reprint of the original 1st ed. 2018 |
| Seiten | 165 |
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