{"product_id":"tin-nano-catalyst-for-bayer-villiger-oxidation-reaction-von-srilatha-konda","title":"Tin Nano Catalyst for Bayer-Villiger Oxidation Reaction","description":"\u003cp\u003eHighly ordered mesoporous SBA-15 silica material was synthesized under hydrothermal conditions using P123 as template and tetraethyl orthosilicate as silica source. Tin nanoparticles were deposited on the pore surfaces of Si-SBA-15 support post synthetically using SnCl4 as tin source. Tin containing SBA-15 catalysts were also prepared by direct synthesis using SnCl4 and SBA-15 precursors under hydrothermal conditions. These Sn-SBA-15 catalysts were further modified by adding trifluromethane sulfonic acid (F3CH-SO3H). These Sn-SBA-15-OTf catalysts were characterized by low angle XRD and N2 adsorption-desorption techniques to investigate the structural intactness of SBA-15 after every modification. The deposition of Sn, its crystalline behavior, particle size, local environments and morphological aspects were characterized by FT-IR, XRD, UV-vis, XPS and SEM techniques respectively. The loading amount of Tf-OH was confirmed by CHNS analysis. Sn-SBA-15-OTf catalyst was found to be highly active and selective towards the Baeyer-Villiger oxidation of cyclohexane to ¿-caprolactone in the liquid phase as heterogeneous catalyst.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783659331206\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9783659331206","offer_id":39447868112989,"sku":"9783659331206","price":39.9,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/5ade8942-7451-4eed-aaa1-f63cbccb3a13.jpg?v=1773727398","url":"https:\/\/shop.autorenwelt.de\/products\/tin-nano-catalyst-for-bayer-villiger-oxidation-reaction-von-srilatha-konda","provider":"Autorenwelt Shop","version":"1.0","type":"link"}