{"product_id":"teoriya-konvergencii-himicheskih-klasterov-von-enos-masheiq-rwantale-kiremire","title":"TEORIYa KONVERGENCII HIMIChESKIH KLASTEROV","description":"\u003cp\u003eCel' ätoj nebol'shoj knigi - pokazat', chto posle analiza i klassifikacii soten himicheskih klasterow, ispol'zuq nowye znaniq teorii klasterow s ee skeletnymi chislami, wyqsnilos', chto wse älementy perehodnyh metallow i ih klastery naceleny na dostizhenie koronnogo parametra klastera K(n)=0(1). Naprimer, Fe(k=5) oznachaet, chto dlq dostizheniq parametra K(n)=0(1) emu trebuetsq pqt' dwuhälektronnyh donorow, i, sledowatel'no, on obrazuet klaster Fe(CO)5. S drugoj storony, Fe2(CO)9 imeet K=1, chto oznachaet, chto emu nuzhen tol'ko 1CO ligand dlq razlozheniq na 2 Fe(CO)5, a Fe3(CO)12 imeet nomer klastera K=3, chto oznachaet, chto esli my dobawim 3CO liganda, to on razlozhitsq na 3 klastera Fe(CO)5, kotorye wse podchinqütsq prawilu 18 älektronow. Analogichno, klaster Os5(CO)16 s K=9 oznachaet, chto esli k nemu dobawit' 9CO ligandow, to on raspadetsq na 5Os(CO)5 monoskeletnyh klasterow, kazhdyj iz kotoryh imeet K(n)=0(1). Vse otobrannye w ätoj knige primery demonstriruüt ätot princip. Krome togo, ustanowleno, chto chisla, otnosqschiesq k walentnym älektronam klasterow, izwestnye kak magicheskie chisla, qwlqütsq walentnymi älektronami klasterow, kotorye prinadlezhat k opredelennym klanowym seriqm, Dz.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9786205320440\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Softcover - 9786205320440","offer_id":40662732865629,"sku":"9786205320440","price":19.8,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/d6fa1c91-2695-40c5-9f94-e1fa9e915a86.jpg?v=1748669071","url":"https:\/\/shop.autorenwelt.de\/products\/teoriya-konvergencii-himicheskih-klasterov-von-enos-masheiq-rwantale-kiremire","provider":"Autorenwelt Shop","version":"1.0","type":"link"}