{"product_id":"syntheses-structures-and-properties-of-feiii-lniii-complexes-using-n-substituted-diethanolamine-ligands-von-sihuai-chen","title":"Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands","description":"\u003cp\u003eIn this thesis, N-substituted diethanolamine ligands have been employed in the syntheses of heterometallic FeIII-LnIII clusters. The reactions of a preformed [FeIII3O]7+ benzoate triangle, LnIII salts and the ligands in different solvents under normal or solvothermal conditions lead to several mixed FeIII-LnIII species with different topologies. Furthermore, new species stabilized under solvothermal conditions can be obtained via a solvothermal treatment of the FeIII-LnIII compounds which result from reactions conducted under normal conditions. The resulting compounds were structurally analyzed by single-crystal X-ray crystallography and X-ray powder diffraction. The magnetic properties and spectroscopic studies were investigated using magnetic susceptibility measurements and Mössbauer spectroscopy. Magnetic studies reveal that three analogous hexanuclear {FeIII4DyIII2} compounds as well as a {FeIII7DyIII4} compound display single molecule magnet behavior.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783954048809\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9783954048809","offer_id":39462926680157,"sku":"9783954048809","price":34.7,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/08a3f9ae-7a83-4f3c-b203-849f8fd06d9f.jpg?v=1780637834","url":"https:\/\/shop.autorenwelt.de\/products\/syntheses-structures-and-properties-of-feiii-lniii-complexes-using-n-substituted-diethanolamine-ligands-von-sihuai-chen","provider":"Autorenwelt Shop","version":"1.0","type":"link"}