{"product_id":"reactivity-of-ylenes-at-late-transition-metal-centers-von-burgert-blom","title":"Reactivity of Ylenes at Late Transition Metal Centers","description":"\u003cp\u003eHeavy main group elements, i.e. those where n \u0026gt; 2, exhibit a marked decreasing propensity to engage in pi- bond formation compared to the lighter elements. This presents a huge challenge in contemporary inorganic chemistry and in terms of triple bonding between heavy main group elements and transition metals, reports are rare. In fact, there are only a few examples of complexes featuring triple bond formation to the heavier homologues of carbon (Si ¿ Pb), and in all these cases the transition metal is always a member of group 6 (Cr, Mo, W).\u003c\/p\u003e\u003cp\u003e\u003c\/p\u003e\u003cp\u003eThis dissertation explores the general reactivity of Power-type ylenes: [EXR] (where E = Ge, Sn and Pb; X = Cl or Br; and R = a bulky m-terphenyl substituent) towards a range of late transition metal complexes in group 8, 9 and 10 with the overall goal of making triple bonds between Ge ¿ Pb with these late transition metal element atoms, hitherto unprecedented.\u003c\/p\u003e\u003cp\u003e\u003c\/p\u003e\u003cp\u003eThe work described here uncovered the first examples of any transition metal beyond group 6 (Fe) engaging in a triple bond interaction to any heavy homologue of carbon.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783869559070\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9783869559070","offer_id":39454222745693,"sku":"9783869559070","price":48.5,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/42597c7e-b1fd-4912-8c51-718e681fb9cc.jpg?v=1782278729","url":"https:\/\/shop.autorenwelt.de\/products\/reactivity-of-ylenes-at-late-transition-metal-centers-von-burgert-blom","provider":"Autorenwelt Shop","version":"1.0","type":"link"}