{"product_id":"physico-chemical-studies-of-metal-complexes-with-n-and-s-donor-ligands-von-ahmad-husain","title":"Physico-chemical studies of metal complexes with N and S donor ligands","description":"\u003cp\u003eThis work describes the physico-chemical studies of metal complexes with N and S donor ligands. Emphasis has been given to the synthesis and characterization of polyazamacrocycles and dithiocarbamato complexes of transition metal ions and Sn(IV). They have been characterized by FT-IR, NMR (1H, 13C and 119Sn), mass spectrometry and X-ray crystallography. The synthesis of 14-membered hexaaza macrocyclic complexes of the type [CuL]X2, [CuL1]X2, [CuL(N3)(ClO4).3\/2O]n, [CuL(N3)2] and [CuL1(N3)(ClO4)]n was reported. The effect of anions on the gross geometry and chemical properties of the Cu(II) ion have been studied. The crystal structure of [Ni(L)][CoCl4] clearly establishes the cationic-anionic interaction. Rare C¿H---Ni anagostic interactions, generally exhibited by d8 complexes also observed. The interaction of potassium bis(2,2-dithiopiperazinato-2,2-diaminodiethylamine (K2L) with R2SnCl2 leading to the formation of bimetallic complexes of the type R4Sn2L2 have been reported. The synthesis of a mononuclear precursor complex, [(CH3)2Sn(tpdtc)] and several heterobimetallic derivatives of the type, [(CH3)2Sn(tpdtc)]MCl2 have also been reported.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783844312218\"\u003e\u003ch3\u003eMacrocyclic complexes, Crystallography, Dithiocarbamates, Anagostic interaction, Organotin, Transition metals\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Softcover - 9783844312218","offer_id":39495940997213,"sku":"9783844312218","price":68.0,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/e1af0e85-e5f8-4913-beae-c542d31eca10.jpg?v=1770529988","url":"https:\/\/shop.autorenwelt.de\/products\/physico-chemical-studies-of-metal-complexes-with-n-and-s-donor-ligands-von-ahmad-husain","provider":"Autorenwelt Shop","version":"1.0","type":"link"}