{"product_id":"nonclassical-crystallization-of-bivalent-metal-carbonates-on-nonclassical-liquid-intermediates-symmetry-breaking-phase-selection-of-metal-carbonates-and-their-morphosynthesis-aided-by-mesocrystallinity-von-stephan-e-wolf","title":"Nonclassical Crystallization of Bivalent Metal Carbonates","description":"\u003cp\u003eSince non-classical crystallization pathways were revealed, our picture of nucleation and crystal growth became in the last year quite confusing and ramified: we are confronted with the existence of liquid phases of amorphous calcium carbonate, polymer-induced liquid precursor and, last but not least, pre-nucleation clusters. This contribution explores: (a) The symmetry-breaking phase-selection of calcium carbonate, which is based upon a subtle interplay of interlinked equilibria and is ultimately ascribed to the weak parity violation energy difference. (b) A morphogenetic employment of mesocrystallinity: the inter-crystalline minority constituent of a mesocrystal, e.g. occluded protein or polymeric additives, experiences compression-molding which can be employed for the preparation of nanotubes of various materials, e.g. calcium carbonate or cadmium sulfide. (c) The existence of a liquid intermediate phase during metal carbonate formation. By a diffusion-controlled and contract-free experimental setup, unequivocally evidence for the existence of nonclassical liquid intermediates, which precede the crystalline phase of bivalent carbonates at near-neutral conditions, is provided.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783838125398\"\u003e\u003ch3\u003eOn nonclassical liquid intermediates, symmetry-breaking phase-selection of metal carbonates, and their morphosynthesis aided by mesocrystallinity\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9783838125398","offer_id":39440639983709,"sku":"9783838125398","price":53.9,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/ae002d06-7379-4399-bcae-b6463811312d.jpg?v=1781240757","url":"https:\/\/shop.autorenwelt.de\/products\/nonclassical-crystallization-of-bivalent-metal-carbonates-on-nonclassical-liquid-intermediates-symmetry-breaking-phase-selection-of-metal-carbonates-and-their-morphosynthesis-aided-by-mesocrystallinity-von-stephan-e-wolf","provider":"Autorenwelt Shop","version":"1.0","type":"link"}