{"product_id":"lithium-ion-conductors-based-on-mil-121-metal-organic-frameworks-a-developing-field-of-solid-state-electrolytes-von-roman-zettl-ilie-hanzu","title":"Lithium-Ion Conductors based on MIL-121 Metal Organic Frameworks","description":"\u003cp\u003eThis work was aimed to investigate a new type of solid state lithium (Li) ion conductor as electrolyte for all solid-state Li-ion batteries. A metal organic framework (MOF) MIL-121 was modified in two different ways in order to become Li-ion conductive. The post synthetic modifications (PSM) were lithiation with lithium acetate (LiAc) and lithium hydroxide (LiOH) as well as esterification of the carboxylic groups of MIL-121 with methanol (MeOH), ethanol (EtOH) and isopropanol. After PSM the porous samples were soaked with different liquids like common liquid electrolytes, which leads to a decreased activation energy of Li-ion jumps in the crystal lattice meaning an increased Li-ion conductivity of the material. Esterified MIL-121 was soaked with ionic liquids containing lithium bis(trifluoromethane)sulfonimide (LiTFSI), because the introduction of Li-ions to the structure was necessary.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9786202207621\"\u003e\u003ch3\u003eA developing Field of Solid State Electrolytes\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9786202207621","offer_id":39455206047837,"sku":"9786202207621","price":35.9,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/25229b14-8e2d-42b6-abed-c27c01a7b229.jpg?v=1773474817","url":"https:\/\/shop.autorenwelt.de\/products\/lithium-ion-conductors-based-on-mil-121-metal-organic-frameworks-a-developing-field-of-solid-state-electrolytes-von-roman-zettl-ilie-hanzu","provider":"Autorenwelt Shop","version":"1.0","type":"link"}