{"product_id":"kinetic-studies-of-reaction-of-benzyloxy-radical-with-oxygen-von-yue-zeng","title":"Kinetic Studies Of Reaction Of Benzyloxy Radical With Oxygen","description":"\u003cp\u003eAlkoxy radicals are key intermediates of the degradation of Volatile Organic  Compounds (VOCs). Of the three major reaction pathways, reaction of alkoxy  radicals with molecular oxygen is more consistently important than  unimolecular decomposition and isomerization. The kinetics of alkoxy radicals  reacting with oxygen has been well studied for small alkoxy radicals derived  from alkanes; however, there was no data for larger alkoxy radicals derived  from more complicated organic compounds, such as aromatic hydrocarbons.  In this study, benzyloxy (C6H5CH2O¿) has been investigated in order to  understand the effect of the aromatic ring on the kinetics of alkoxy radicals  reaction with oxygen. The ratio of reactions benzyloxy with oxygen and  versus nitrogen dioxide has been investigated by relative rate constant  method with product determination by GC-FID. Then rate constants of these  two reactions have been estimated and input in kinetic model by Kintecus  software. Model and experiment results have been compared and  suggestions for improvement have been addressed.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783659157943\"\u003e\u003ch3\u003eBy Relative Rate Constant Method\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Softcover - 9783659157943","offer_id":39489853849693,"sku":"9783659157943","price":49.0,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/dc0cdb64-4c09-47a2-81a0-bd5899077d2e.jpg?v=1769667437","url":"https:\/\/shop.autorenwelt.de\/products\/kinetic-studies-of-reaction-of-benzyloxy-radical-with-oxygen-von-yue-zeng","provider":"Autorenwelt Shop","version":"1.0","type":"link"}