{"product_id":"kataliz-5-monofosfata-orotidina-vychislitelnoe-issledowanie-von-diana-shem","title":"Kataliz 5'-monofosfata orotidina","description":"\u003cp\u003eV kachestwe modeli wzaimodejstwij, prisutstwuüschih w aktiwnom centre orotidin-5'-monofosfat dekarboxilazy (ODCase), my issledowali äffekty destabilizacii substrata blizlezhaschim otricatel'nym zarqdom i stabilizacii karbanionnogo intermediata za schet wodorodnyh swqzej s karbonil'nymi gruppami ( O-2 i O-4) orotowoj kisloty i produkta ee dekarboxilirowaniq s ispol'zowaniem raschetow ab initio. Rezul'taty ätih modelej byli sopostawimy s dostupnymi dannymi, predpolagaq, chto welichina uwelicheniq skorosti dekarboxilirowaniq zawisit ot kombinacii zarqdowogo rasstoqniq i äffektow wodorodnyh swqzej. My obnaruzhili, chto dipol'nyj moment donora protona takzhe mozhet igrat' znachitel'nuü rol', podrazumewaq, chto klüch k ostal'noj chasti kataliza lezhit w konkretnyh wzaimodejstwiqh substrata i okruzhaüschih ostatkow.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9786203298123\"\u003e\u003ch3\u003eVychislitel'noe issledowanie\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9786203298123","offer_id":39461014339677,"sku":"9786203298123","price":49.0,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/0ec4159d-15b6-4bfa-a02f-6943cdd73c30.jpg?v=1757398998","url":"https:\/\/shop.autorenwelt.de\/products\/kataliz-5-monofosfata-orotidina-vychislitelnoe-issledowanie-von-diana-shem","provider":"Autorenwelt Shop","version":"1.0","type":"link"}