{"product_id":"garners-aldehyde-an-important-chiral-a-amino-aldehyde-in-organic-chemistry-von-moumita-ghosh","title":"Garner's aldehyde","description":"\u003cp\u003eChiral amino aldehydes are remarkable, as their aldehyde groups can be converted into a wide range of structural frameworks are the intermediates in several important industrial processes. However, the characteristic reactivity of amine and aldehyde functionalities is a major task in case of preparation and synthetic efficacy of ¿-amino aldehydes as nitrogen protection assists undesired epimerization processes. Fischer¿s discovery of glucosamine in 1902 in which unprotected amine and aldehyde functionalities are stabilized as a cyclic hemiacetal is the first example of unprotected ¿-amino aldehydes. Later on, he also synthesized glycinal, which was characterized through degradation studies due to its inherent instability via self-condensation. The probability for intramolecular stabilization of ¿-amino aldehydes is not significant but the presence of incompatible functional groups make these unstable and hence, suitable N-and C-protection is vital.\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9786200275783\"\u003e\u003ch3\u003eAn important chiral ¿- amino aldehyde in organic chemistry\u003c\/h3\u003e\u003c\/div\u003e","brand":"Libri","offers":[{"title":"Softcover - 9786200275783","offer_id":39464561410141,"sku":"9786200275783","price":39.9,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/e613029e-5bfb-4302-a203-54a0a619364e.jpg?v=1773732520","url":"https:\/\/shop.autorenwelt.de\/products\/garners-aldehyde-an-important-chiral-a-amino-aldehyde-in-organic-chemistry-von-moumita-ghosh","provider":"Autorenwelt Shop","version":"1.0","type":"link"}