{"product_id":"enantioselective-electrochemical-c-h-activation-enabled-by-sustainable-3d-transition-metal-catalysis-von-sven-erik-peters","title":"Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis","description":"\n                                \n                \u003cp\u003e\n                                        Enantioselective metallaelectro-catalyzed C─H activation represents an innovative strategy for enabling the transition of organic synthesis to a more resource-economic mode of operation. It circumvents substrate prefunctionalization by directly exploiting otherwise inert C─H bonds to construct complex three-dimensional scaffolds from simple molecular building blocks. Furthermore, the mild electrocatalytic conditions evade chemical oxidants, while producing molecular hydrogen as the sole by-product, enabling the connection of organic synthesis to a possible future decentralized green hydrogen economy.\n                    \n                    \u003cbr\u003e\n                                        Still, disclosed methodologies predominantly rely on noble metal catalysts. Examples using earth-abundant 3d transition metals remain scarce despite the substantially improved ecological and economic implications and diminished toxicity. This work addresses this shortcoming by investigating the first enantioselective nickelaelectro-catalyzed C─H activation and various cobaltaelectro-catalyzed conversions. On this occasion, the synthetic versatility is examined and various mechanistic experiments are presented for fostering future developments.\n                \n                \u003c\/p\u003e\n                            \n            \u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783658471095\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Softcover - 9783658471095","offer_id":54234948632901,"sku":"9783658471095","price":106.99,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/8ada6517-89c2-456c-978d-93eeab826737.jpg?v=1776922778","url":"https:\/\/shop.autorenwelt.de\/products\/enantioselective-electrochemical-c-h-activation-enabled-by-sustainable-3d-transition-metal-catalysis-von-sven-erik-peters","provider":"Autorenwelt Shop","version":"1.0","type":"link"}