{"product_id":"design-synthesis-and-properties-of-redox-active-bisquinodimethanes-von-takashi-harimoto","title":"Design, Synthesis, and Properties of Redox-Active Bisquinodimethanes","description":"\n                                \n                \u003cp\u003e\n                                        This book focuses on the construction of redox systems composed of doubly fused \n                    \n                    \u003cem\u003epara\u003c\/em\u003e\n                                        -quinodimethane (\n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD) units and on the elucidation of the unique redox behavior. \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD is a class of non-aromatic π-conjugated compounds that is well-known to be interconvertible scaffolds in many response systems due to its contribution of resonance structure with a planar aromatic sextet ring. This book describes studies on a strategy for precisely controlling the frontier orbital levels of \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD-based redox systems and a nature of cationic states of π-electron systems with doubly fused \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD units. The author revealed that multi-redox unimolecular systems with cross-linking of the two sterically strained \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD units exhibit unique hysteretic character or have a domino effect upon electron transfer, which cannot be achieved in a monomeric \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD-based system. Thus, these studies are milestones in creating functional redox systems unprecedented dynamic redox (\n                    \n                    \u003cem\u003edyrex\u003c\/em\u003e\n                                        ) behaviors. A study on cationic states of π-electron systems with doubly fused \n                    \n                    \u003cem\u003ep\u003c\/em\u003e\n                                        -QD units and their intrinsic redox properties will lead to the development of unprecedented \n                    \n                    \u003cem\u003edyrex \u003c\/em\u003e\n                                        systems, the frontier orbital levels of which can be precisely controlled by input of external stimuli such as electric potential and heat. This book benefits chemists with a deeper understanding of the redox-active molecules.\n                \n                \u003c\/p\u003e\n                            \n            \u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9789819615902\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9789819615933\"\u003e\u003ch3\u003e\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Hardcover - 9789819615902","offer_id":54113129300293,"sku":"9789819615902","price":213.99,"currency_code":"EUR","in_stock":true},{"title":"Softcover - 9789819615933","offer_id":57952096092485,"sku":"9789819615933","price":235.39,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/6e524432-3912-4d96-8bad-034e7a05046b.jpg?v=1778819963","url":"https:\/\/shop.autorenwelt.de\/products\/design-synthesis-and-properties-of-redox-active-bisquinodimethanes-von-takashi-harimoto","provider":"Autorenwelt Shop","version":"1.0","type":"link"}