{"product_id":"synthesis-and-characterize-schiff-base-compound-von-nadiah-ameram-und-uwaisulqarni-othman","title":"Synthesis and characterize Schiff Base compound","description":"\u003cp\u003eA new Schiff Base ligand [(SBDTC)2AP] has been synthesized by the 1:2 condensation of Acetophenone and S-benzyldithiocarbazate. A group of selected ions such as Cu(II), Cd(II), Zn(II), Ni(II) and Co(II) complexes of [(SBDTC)2AP] have been prepared and characterized by elemental analysis, spectroscopic studies and various physico-chemical techniques included melting point determination, IR spectra and Uv-Vis spectra. Melting point of Schiff base is basically lower than metal complexes because of intra-molecular interaction. The FTIR spectrum for Schiff base ligand shows stretching vibration of the important functional group ;v(N-H) in range ~3179 cm-1,v(C=S) in range ~1103cm-1,v(N-N-C) in range ~1344cm-1,v(C=N) in range  ~ 1599 cm-1 and lastly v(C-S-S) in range of 1027 cm-1.As for the metal complexes of Schiff base, they posses in thiol form in solid state because of the v(N-H) and v(C=S) stretching disappearance near 3179 cm-1 and 1103 cm-1 respectively. The coordination of the azomethine nitrogen and sulfur donors atom to the metal is indicate by the shift on the v(C=N) band  at 1599 cm-1 and in the v(C-S-S) band at 921 cm-1 .\u003c\/p\u003e\u003cdiv class=\"aw-variant-hidden-subtitle-div\" id=\"aw-variant-subtitle-9783659115691\"\u003e\u003ch3\u003eCo(II), Cu(II), Cd(II), Zn(II) and Ni(II) Complex of Schiff Base ligand with acetophenone\u003c\/h3\u003e\u003c\/div\u003e","brand":"Autorenwelt Shop","offers":[{"title":"Softcover - 9783659115691","offer_id":39484206088285,"sku":"9783659115691","price":35.9,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0940\/0622\/files\/6d8de0ed-349b-42a0-b94f-0b3e44a463fa.jpg?v=1773727944","url":"https:\/\/shop.autorenwelt.de\/en\/products\/synthesis-and-characterize-schiff-base-compound-von-nadiah-ameram-und-uwaisulqarni-othman","provider":"Autorenwelt Shop","version":"1.0","type":"link"}